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While the low-energy side of the ΔAcurves remains stable over time, the high-energy side changes dramatically, reflecting hot carrier thermalization, which occurs at different rates on the hole and electron transport sides in perovskite solar cells.more » « lessFree, publicly-accessible full text available October 20, 2026
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Afshari, Hadi; Sourabh, Shashi; Chacon, Sergio A.; Whiteside, Vincent R.; Penner, Rachel C.; Rout, Bibhudutta; Kirmani, Ahmad R.; Luther, Joseph M.; Eperon, Giles E.; Sellers, Ian R. (, ACS Energy Letters)Prashant V. Kamat (Ed.)Formamidinium cesium (FACs) perovskites solar cells have been shown to be among the most stable metal halide perovskites. Here, high-temperature data are presented which systematically and statistically demonstrate the high thermal operation of this system to temperatures in excess of 200 °C. Device measurements between 250 K and 490 K show that while some loss of performance is evident at higher temperature, this is driven by reversible halide segregation with no evidence of a structural phase transition over the measurement range probed. Moreover, upon reduction of the temperature back to ambient the power conversion efficiency is retained.more » « less
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Jariwala, Sarthak; Kumar, Rishi E.; Eperon, Giles E.; Shi, Yangwei; Fenning, David P.; Ginger, David S. (, ACS Energy Letters)
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Birkhold, Susanne T.; Precht, Jake T.; Liu, Hongbin; Giridharagopal, Rajiv; Eperon, Giles E.; Schmidt-Mende, Lukas; Li, Xiaosong; Ginger, David S. (, ACS Energy Letters)
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